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Author(s):   Wallington, T.J.; Hurley, M.D.; Fedotov, V.; Morrell, C.; Hancock, G.
Title:   Atmospheric Chemistry of CF3CH2OCHF2 and CF3CHClOCHF2: Kinetics and Mechanisms of Reaction with Cl Atoms and OH Radicals and Atmospheric Fate of CF3C(O·)HOCHF2 and CF3C(O·)ClOCHF2 Radicals
Journal:   J. Phys. Chem. A
Volume:   106
Page(s):   8391 - 8398
Year:   2002
Reference type:   Journal article
Squib:   2002WAL/HUR8391-8398

Reaction:   ·Cl + CHF2OCHClCF3 → Products
Reaction order:   2
Reference reaction:   CH4 + ·Cl → Products
Reference reaction order:   2
Temperature:   295 K
Pressure:  0.93 bar
Rate expression:   5.5x10-15±1.7x10-15
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In both real time and by end product analysis
Analytical technique:   Fourier transform (FTIR)
Comments:   Relative rate measurement (reference reactions Cl + CH4 and Cl + CD4), pyrex reactor with FTIR, Cl from photolysis of Cl2, mechanistic information on Cl reactions and product yields from OH reactions also determined

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