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Author(s):   Andersen, M.PS.; Nielsen, O.J.; Karpichev, B.; Wallington, T.J.; Sander, S.P.
Title:   Atmospheric Chemistry of Isoflurane, Desflurane, and Sevoflurane: Kinetics and Mechanisms of Reactions with Chlorine Atoms and OH Radicals and Global Warming Potentials
Journal:   J. Phys. Chem. A
Volume:   116
Page(s):   5806 - 5820
Year:   2012
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2012AND/NIE5806-5820

Reaction:   ·Cl + CHF2OCHClCF3 → Products
Reaction order:   2
Temperature:   295 K
Pressure:  0.93 bar
Rate expression:   4.5x10-15 [±8.0x10-16 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Fourier transform (FTIR)
Comments:   Deuterated methane and 1,1,1,2-tetrafluoroethane were used as reference compounds. The quoted value is the average of the individual determinations with error limits which encompass the extremes of the individual determinations.

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