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Author(s):   Zhao, Z.; Huskey, D.T.; Nicovich, J.M.; Wine, P.H.
Title:   Temperature-dependent kinetics study of the gas-phase reactions of atomic chlorine with acetone, 2-butanone, and 3-pentanone
Journal:   Int. J. Chem. Kinet.
Volume:   40
Page(s):   259 - 267
Year:   2008
Reference type:   Journal article
Squib:   2008ZHA/HUS259-267

Reaction:   Acetone + ·Cl → Products
Reaction order:   2
Temperature:   210 - 440 K
Pressure:  4.00E-2 - 0.40 bar
Rate expression:   1.53x10-11 [±1.9x10-12 cm3/molecule s] e-4939 [±274 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Resonance fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
210 9.04E-13
225 1.09E-12
250 1.42E-12
275 1.76E-12
300 2.11E-12
325 2.46E-12
350 2.80E-12
375 3.14E-12
400 3.47E-12
425 3.78E-12
440 3.97E-12