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Accessibility information
Author(s):   Levush, S.S.; Abadzhev, S.S.; Shevchuk, V.U.
Title:   Thermal conversions of methylacetylene and allene
Journal:   Neftekhimiya
Volume:   9
Year:   1969
Reference type:   Journal article
Squib:   1969LEV/ABA215

Reaction:   CH3CCH → Other Products + C2H2
Reaction order:   1
Temperature:   1170 - 1420 K
Pressure:  1.01 bar
Rate expression:   4.2x109 [s-1] e-217008 [J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1170 8.61E-1
1175 9.47E-1
1200 1.50E0
1225 2.34E0
1250 3.59E0
1275 5.41E0
1300 8.02E0
1325 1.17E1
1350 1.69E1
1375 2.40E1
1400 3.36E1
1420 4.37E1