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Accessibility information
Author(s):   Wallington, T.J.;Hurley, M.D.;Haryanto, A.
Title:   Kinetics of the gas phase reactions of chlorine atoms with a series of formates
Journal:   Chem. Phys. Lett.
Volume:   432
Page(s):   57 - 61
Year:   2006
Reference type:   Journal article
Squib:   2006WAL/HUR57-61

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2006WAL/HUR57-61   HC(O)OCH3 + ·Cl → Products  296   2.79              2
  Reference reaction:  CH3Cl + ·Cl → Products 2
  2006WAL/HUR57-61   HC(O)OCH3 + ·Cl → Products  296   0.16              2
  Reference reaction:  C2H5Cl + ·Cl → Products 2
  2006WAL/HUR57-61   HC(O)OC2H5 + ·Cl → Products  296   1.13              2
  Reference reaction:  C2H5Cl + ·Cl → Products 2
  2006WAL/HUR57-61   HC(O)OC2H5 + ·Cl → Products  296   0.20              2
  Reference reaction:  C2H2 + ·Cl → Products 2
  2006WAL/HUR57-61   HCOOCH2CH2CH3 + ·Cl → Products  296   5.59              2
  Reference reaction:  C2H5Cl + ·Cl → Products 2
  2006WAL/HUR57-61   HCOOCH2CH2CH3 + ·Cl → Products  296   0.95              2
  Reference reaction:  C2H2 + ·Cl → Products 2
  2006WAL/HUR57-61   HCOO(CH2)3CH3 + ·Cl → Products  296   2.11              2
  Reference reaction:  C2H2 + ·Cl → Products 2
  2006WAL/HUR57-61   HCOO(CH2)3CH3 + ·Cl → Products  296   1.25              2
  Reference reaction:  C2H4 + ·Cl → Products 2
  2006WAL/HUR57-61   HC(O)OCH3 + ·Cl → Products  296   1.30E-12              2
  2006WAL/HUR57-61   HC(O)OC2H5 + ·Cl → Products  296   9.57E-12              2
  2006WAL/HUR57-61   HCOOCH2CH2CH3 + ·Cl → Products  296   4.65E-11              2
  2006WAL/HUR57-61   HCOO(CH2)3CH3 + ·Cl → Products  296   1.12E-10              2
Search returned 12 records.