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Title: The mechanism of thermal eliminations. Part 26. Substituent effects at carbon of vinyl ethers: non-planarity of the transition state
Journal: J. Chem. Soc. Perkin Trans. 2
Page(s): 737 - 743
Year: 1988
Reference type: Journal article
Squib: 1988TAY737-743
Reaction:
Benzene, [1-(1-methylethoxy)ethenyl]-3-nitro- → Ethanone, 1-(4-nitrophenyl)- + CH3CH=CH2
Reaction order:
1
Temperature:
600 - 652
K
Rate expression:
2.57x1012 [s-1] e-168784 [J/mole]/RT
Bath gas:
Benzene, [1-(1-methylethoxy)ethenyl]-3-nitro-
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Time resolution:
In real time
Analytical technique:
IR absorption
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 600 | 5.20E-3 |
| 625 | 2.01E-2 |
| 650 | 7.02E-2 |
| 652 | 7.73E-2 |