Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Taylor, R.
Title:   The mechanism of thermal eliminations. Part 26. Substituent effects at carbon of vinyl ethers: non-planarity of the transition state
Journal:   J. Chem. Soc. Perkin Trans. 2
Page(s):   737 - 743
Year:   1988
Reference type:   Journal article
Squib:   1988TAY737-743

Reaction:   Benzene, [1-(1-methylethoxy)ethenyl]-3-nitro- → Ethanone, 1-(4-nitrophenyl)- + CH3CH=CH2
Reaction order:   1
Temperature:   600 - 652 K
Rate expression:   2.57x1012 [s-1] e-168784 [J/mole]/RT
Bath gas:   Benzene, [1-(1-methylethoxy)ethenyl]-3-nitro-
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   IR absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
600 5.20E-3
625 2.01E-2
650 7.02E-2
652 7.73E-2