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Author(s):   Wright, S.M.A.; Sims. I.R.; Smith, I.W.M.
Title:   Vibrational Relaxation of Highly Excited NCNO in Collisions with He, Ar and N2
Journal:   Phys. Chem. Chem. Phys.
Volume:   3
Page(s):   2203 - 2208
Year:   2001
Reference type:   Journal article
Squib:   2001WRI/SIM2203-2208

Reaction:   NCNO(Ev~10,000 cm-1) + Ar → NCNO(Ev~10,000 cm-1) + Ar
Reaction order:   2
Rate expression:   no rate data available
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Other (IR)
Comments:   Assuming Lennard-Jones collision parameters and other assumptions relating IR emission intensity to internal excitation, the measurements indicate that NCNO contining approximately 10,000 cm-1 vibrational excitation will lose 0.44 cm-1 per collision with helium.

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