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Author(s):   Baren, R.E.; Hershberger, J.F.
Title:   Kinetics of the NCS Radical
Journal:   J. Phys. Chem. A
Volume:   103
Page(s):   11340 - 11344
Year:   1999
Reference type:   Journal article
Squib:   1999BAR/HER11340-11344

Reaction:   C2H2 + SCN → Products
Reaction order:   2
Temperature:   298 - 620 K
Pressure:  2.67E-3 bar
Rate expression:   1.0x10-14 [cm3/molecule s]
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence
Comments:   This is the first report of the kinetics of NCS radical, the rate constant is the upper limit.

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