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Author(s):   Yang, K.
Title:   Free radical reactions initiated by ionizing radiations. III. Paraffin reactivities in hydrogen atom abstraction reactions
Journal:   J. Phys. Chem.
Volume:   67
Year:   1963
Reference type:   Journal article
Squib:   1963YAN562

Reaction:   iso-C4H10 + → Other Products + H2
Reaction order:   2
Reference reaction:   CH3CH=CH2 + → Products
Reference reaction order:   2
Temperature:   270 - 435 K
Rate expression:   3.63x10-1 e-10310 [±8314472 J/mole]/RT
Uncertainty:   1.35000002
Bath gas:   Ar
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Ultrasonics
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
270 3.68E-3
275 4.00E-3
300 5.82E-3
325 8.00E-3
350 1.05E-2
375 1.33E-2
400 1.64E-2
425 1.96E-2
435 2.10E-2