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Title: Rate parameters for reaction of atomic selenium with olefins
Journal: Trans. Faraday Soc.
Volume: 62
Page(s): 2760 - 2767
Year: 1966
Reference type: Journal article
Squib: 1966CAL/TYE2760-2767
Reaction:
(E)-2-C4H8 + Se → Adduct
Reaction order:
2
Reference reaction:
C2H4 + Se → Selenirane
Temperature:
302 - 418
K
Pressure: 6.67E-2 bar
Rate expression:
2.91x10-11 [±1.31x10-11 cm3/molecule s] e-2461 [±8314472 J/mole]/RT
Bath gas:
N2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Direct photolysis
Analytical technique:
Other (direct)
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 302 | 1.09E-11 |
| 325 | 1.17E-11 |
| 350 | 1.25E-11 |
| 375 | 1.32E-11 |
| 400 | 1.39E-11 |
| 418 | 1.43E-11 |