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Accessibility information
Author(s):   Callear, A.B.; Tyerman, W.J.R.
Title:   Rate parameters for reaction of atomic selenium with olefins
Journal:   Trans. Faraday Soc.
Volume:   62
Page(s):   2760 - 2767
Year:   1966
Reference type:   Journal article
Squib:   1966CAL/TYE2760-2767

Reaction:   (E)-2-C4H8 + Se → Adduct
Reaction order:   2
Reference reaction:   C2H4 + Se → Selenirane
Temperature:   302 - 418 K
Pressure:  6.67E-2 bar
Rate expression:   2.91x10-11 [±1.31x10-11 cm3/molecule s] e-2461 [±8314472 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Other (direct)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
302 1.09E-11
325 1.17E-11
350 1.25E-11
375 1.32E-11
400 1.39E-11
418 1.43E-11