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Author(s):   Gowenlock, B.G.; Thomas, K.E.
Title:   Gas-phase reactions of sodium. Part I. Rates of reaction of methylchlorosilanes and the analogous carbon compounds
Journal:   J. Chem. Soc. A
Year:   1965
Reference type:   Journal article
Squib:   1965GOW/THO5068

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1965GOW/THO5068   CCl4 + Na·CCl3 + NaCl  520   3.75E-10              2
  1965GOW/THO5068   CH3CCl3 + NaNaCl + CH3CCl2·  520   6.53E-11              2
  1965GOW/THO5068   (CH3)3SiCl + NaNaCl + (CH3)3Si·  520   4.13E-15              2
  1965GOW/THO5068   (CH3)2SiCl2 + NaNaCl + Silyl, chlorodimethyl-  520   3.39E-15              2
  1965GOW/THO5068   CH3SiCl3 + NaNaCl + Silyl, dichloromethyl-  520   9.75E-15              2
  1965GOW/THO5068   Bromobenzene + NaPhenyl + NaBr  520   1.91E-12              2
  1965GOW/THO5068   tert-C4H9Cl + Natert-C4H9 + NaCl  520   4.58E-13              2
  1965GOW/THO5068   (CH3)2CCl2 + NaNaCl + (CH3)2CCl  520   7.02E-12              2
  1965GOW/THO5068   Na + SiCl4NaCl + SiCl3  520   1.15E-12              2

Search returned 9 records.