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Author(s):   Jakubowski, E.; Ahmed, M.G.; Lown, E.M.; Sandhu, H.S.; Gosavi, R.K.; Strausz, O.P.
Title:   Sulfur Atom Abstraction from Episulfides and Carbonyl Sulfide by Methyl Radicals
Journal:   J. Am. Chem. Soc.
Volume:   94
Page(s):  
Year:   1972
Reference type:   Journal article
Squib:   1972JAK/AHM4094

Reaction:   Thiirane + CH3C2H4 + CH3SS
Reaction order:   2
Reference reaction:   CH3 + CH3(CH3S)2
Temperature:   304 - 478 K
Rate expression:   5.25x10-13 [cm3/molecule s] e-36833 [J/mole]/RT
Uncertainty:   1.77999997
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
304 2.46E-19
325 6.31E-19
350 1.67E-18
375 3.89E-18
400 8.13E-18
425 1.56E-17
450 2.78E-17
475 4.67E-17
478 4.95E-17