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Author(s):   Riva, M.; Healy, R. M.; Flaud, P. M.; Perraudin, E.; Wenger, J. C.; Villenave, E.
Title:   Kinetics of the Gas-Phase Reactions of Chlorine Atoms with Naphthalene, Acenaphthene, and Acenaphthylene
Journal:   J. Phys. Chem. A
Volume:   118
Page(s):   3535 - 3540
Year:   2014
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2014RIV/HEA3535-3540

Reaction:   Acenaphthylene + ·Cl → Products
Reaction order:   2
Reference reaction:   CH2=C(CH3)CH=CH2 + ·Cl → Products
Temperature:   293 K
Pressure:  1.01 bar
Rate expression:   4.13x10-10 [±3.4x10-11 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Mass spectrometry
Comments:   The indicated errors are two least-squares standard deviations and do not include the uncertainty in the reference rate constant, which may add up to a further 20% to the error.

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