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Author(s):   Tsang, W.
Title:   Rate constants for the decomposition and formation of simple alkanes over extended temperature and pressure ranges
Journal:   Combust. Flame
Volume:   78
Page(s):   71 - 86
Year:   1989
Reference type:   Journal article
Squib:   1989TSA71-86

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1989TSA71-86   CH4·CH3 +   995 - 2700   3.70E15       4.34E05      1
  1989TSA71-86   C2H6·CH3 + ·CH3  843 - 2500   1.12E18   -1.79   3.81E05      1
  1989TSA71-86   C3H8·C2H5 + ·CH3  773 - 2500   2.94E18   -1.79   3.71E05      1
  1989TSA71-86   iso-C4H102-C3H7 + ·CH3  713 - 2000   3.84E19   -2.61   3.78E05      1
  1989TSA71-86   2-C3H7 + ·CH3iso-C4H10  713 - 1800   4.28E-11   -0.57          2
  1989TSA71-86   ·CH3 + ·CH3C2H6  298 - 2000   4.43E-11   -0.64       4.43E-11  2
  1989TSA71-86   ·CH3 + CH4  293 - 750   2.04E-10   -0.40       2.04E-10  2
  1989TSA71-86   ·C2H5 + ·CH3C3H8  773 - 2300   5.16E-11   -0.32          2

Search returned 8 records.