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Title: The addition of methyl radicals to hexafluoroacetone
Journal: Int. J. Chem. Kinet.
Volume: 16
Page(s):
Year: 1984
Reference type: Journal article
Squib: 1984BAT/MOW603
Reaction:
(CF3)2CO + ·CH3 → CH3COCF3 + ·CF3
Reaction order:
2
Reference reaction:
·CH3 + ·CH3 → C2H6
Temperature:
402 - 433
K
Pressure: 5.07E-2 - 0.15 bar
Rate expression:
1.66x10-13 [cm3/molecule s] e-21368 [±2985 J/mole]/RT
Uncertainty:
2.0
Bath gas:
H2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 402 | 2.78E-16 |
| 425 | 3.93E-16 |
| 433 | 4.39E-16 |