 |
Home ©NIST, 2023 Accessibility information |
Contact Us to Submit an Article
Other Databases
NIST Standard Reference Data Program
NDRL-NIST Solution Kinetics Database
NIST Computational Chemistry Comparison and Benchmark Database
The NIST Reference on Constants, Units, and Uncertainty
Administrative Links
Title: Kinetics of the gas-phase reactions of OH radicals with a series of trimethylphenols
Journal: Int. J. Chem. Kinet.
Volume: 44
Page(s): 117 - 124
Year: 2012
Reference type: Journal article
Squib: 2012BEJ/SCH117-124
Reaction:
Phenol, 2,3,5-trimethyl- + ·OH → Products
Reaction order:
2
Temperature:
298
K
Pressure: 1.33E-3 bar
Rate expression:
1.48x10-10 [±4.2x10-11 cm3/molecule s]
Category: Experiment
Data type:
Relative value normalized by a reference value
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Direct photolysis
Time resolution:
By end product analysis
Analytical technique:
Fourier transform (FTIR)
Comments:
Average of the two values obtained using 1,3-butadiene and isoprene as reference compounds. The quoted errors includes the 2σ statistical errors obtained from the linear regression analysys plus a 20% contribution to cover possible errors in the recommended values of the rate coefficients for reference compounds with OH, and also the errors arising from the IR spectral subtraction procedure.
View full bibliographic record.