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Author(s):   Van Mele, B.; Huybrechts, G.
Title:   Kinetics, mechanism, and stereochemistry of diels-alder reactions of CN-substituted ethenes with cyclohexa-1,3-diene in the gas phase
Journal:   Int. J. Chem. Kinet.
Volume:   19
Page(s):  
Year:   1987
Reference type:   Journal article
Squib:   1987VAN/HUY363

Reaction:   CH2=C(CH3)CN + 1,3-Cyclohexadiene → Adduct
Reaction order:   2
Temperature:   458 - 559 K
Pressure:  9.33E-2 - 0.25 bar
Rate expression:   1.78x10-15 [cm3/molecule s] e-97279 [±209525 J/mole]/RT
Uncertainty:   1.10000002
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
458 1.43E-26
475 3.57E-26
500 1.22E-25
525 3.72E-25
550 1.03E-24
559 1.44E-24