NIST Chemical Kinetics Database

Author(s):   Kaufman, E.D.; Reed, J.F.
Title:   The vapor phase diffusion flame reaction of sodium with fluorinated chloromethanes
Journal:   J. Chem. Phys.
Volume:   67
Page(s):
Year:   1963
Reference type:   Journal article
Squib:   1963KAU/REE896

Reaction:   CF₂Cl₂ + Na → ·CClF₂ + NaCl
Reaction order:   2
Temperature:   519 - 583 K
Pressure:  6.67E-4 - 1.33E-2 bar
Rate expression:   1.53x10^-9 [cm³/molecule s] e^{-37665 [J/mole]/RT}
Bath gas:   N2
Category: Theory
Data type:   Estimated: thermochemical, kinetic, or other

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Rate constant values calculated from the Arrhenius expression:

T (K)	k(T) [cm³/molecule s]
519	2.48E-13
525	2.74E-13
550	4.06E-13
575	5.81E-13
583	6.47E-13