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Accessibility information
Author(s):   Cobos, C.J.; Troe, J.
Title:   Theory of thermal unimolecular reactions at high pressures. II. Analysis of experimental results
Journal:   J. Chem. Phys.
Volume:   83
Page(s):   1010 - 1015
Year:   1985
Reference type:   Journal article
Squib:   1985COB/TRO1010-1015

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1985COB/TRO1010-1015   CD3 + CD3C2D6  300 - 1400   5.75E-11       299      2
  1985COB/TRO1010-1015   CH3 + ·CH3 + O2  300 - 2300   3.55E-11       1987      2
  1985COB/TRO1010-1015   Benzyl + Toluene  300 - 1500   7.69E-10       2112      2
  1985COB/TRO1010-1015   ·CH3 + ·CH3C2H6  300 - 1300   5.63E-11       449      2
  1985COB/TRO1010-1015   ·CH3 + NF2 → Adduct  300 - 1500   1.35E-11       4756      2
  1985COB/TRO1010-1015   ·CH3 + O2CH3O2·  298 - 1500   6.44E-12       2661   2.20E-12  2
  1985COB/TRO1010-1015   ·CH3 + NOCH3NO  300 - 1500   2.27E-11       1048      2
  1985COB/TRO1010-1015   ·CH3 + CH4  300 - 2200   4.48E-10       1671      2
  1985COB/TRO1010-1015   ·CF3 + ·CF3C2F6  300 - 1300   2.31E-11              2
  1985COB/TRO1010-1015   ·CF3 + O2CF3O2  300 - 1500   2.59E-11       2611      2
  1985COB/TRO1010-1015   ·CF3 + NOCF3NO  300 - 900   7.31E-12       1098      2
  1985COB/TRO1010-1015   ·CF3 + ICF3I  300 - 1500   2.01E-11       2054      2
  1985COB/TRO1010-1015   ·CCl3 + ·CCl3CCl3CCl3  300 - 1500   8.40E-12       -432      2
  1985COB/TRO1010-1015   ·OH + SO2HOSO2  300 - 1500   2.74E-12       665      2
  1985COB/TRO1010-1015   ·OH + H2O  300 - 2100   2.69E-10       624      2
  1985COB/TRO1010-1015   ·OH + O2 +   300 - 2500   2.79E-11       99.77      2
  1985COB/TRO1010-1015   O2 + HO2  298 - 1500   2.71E-11       3184   7.49E-12  2
  1985COB/TRO1010-1015   O2 + O3  300 - 2100   5.80E-12       1904      2
  1985COB/TRO1010-1015   NO + IINO  300 - 2100   1.94E-11       324      2
  1985COB/TRO1010-1015   NO + NO2  300 - 2100   3.59E-11       449      2
  1985COB/TRO1010-1015   NO + ·ClNOCl  300 - 2100   6.03E-11       99.77      2
  1985COB/TRO1010-1015   NO2 + NO2N2O4  300   8.30E-13              2
  1985COB/TRO1010-1015   NO2 + IINO2  300 - 1500   4.22E-11       -1081      2
  1985COB/TRO1010-1015   NO2 + NO3N2O5  295 - 520   1.81E-12       815   1.30E-12  2
  1985COB/TRO1010-1015   NO2 + NO3  300 - 1500   2.71E-11       524      2

Search returned 25 records.