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Author(s):   Ballesteros, B.;Garzon, A.;Jimenez, E.;Notario, A.;Albaladejo, J.
Title:   Relative and absolute kinetic studies of 2-butanol and related alcohols with tropospheric Cl atoms
Journal:   Phys. Chem. Chem. Phys.
Volume:   9
Page(s):   1210 - 1218
Year:   2007
Reference type:   Journal article
Squib:   2007BAL/GAR1210-1218

Reaction:   sec-C4H9OH + ·Cl → Products
Reaction order:   2
Temperature:   267 - 384 K
Pressure:  6.67E-2 - 0.27 bar
Rate expression:   6.16x10-11 [±5.8x10-12 cm3/molecule s] e1447 [±482 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence
Comments:   Error limits are one sigma.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
267 1.18E-10
275 1.16E-10
300 1.10E-10
325 1.05E-10
350 1.01E-10
375 9.80E-11
384 9.69E-11