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Title: The thermolysis and photolysis of malonic acid in the gas phase
Journal: Can. J. Chem.
Volume: 64
Page(s):
Year: 1986
Reference type: Journal article
Squib: 1986CAO/BAC967
Reaction:
CH2(COOH)2 → CH3C(O)OH + CO2
Reaction order:
1
Temperature:
365 - 424
K
Pressure: 1.33E-4 bar
Rate expression:
1.86x1013 [s-1] e-129706 [J/mole]/RT
Bath gas:
CH2(COOH)2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 365 | 5.10E-6 |
| 375 | 1.60E-5 |
| 400 | 2.15E-4 |
| 424 | 1.95E-3 |