Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Huang, C-L.; Wu, C-C.; Lien, M-H.
Title:   Ab initio studies of decarboxylations of the β-keto carboxylic acids XCOCH2COOH (X=H, OH, and CH3)
Journal:   J. Phys. Chem. A
Volume:   101
Page(s):   7867 - 7873
Year:   1997
Reference type:   Journal article
Squib:   1997HUA/WU7867-7873

Reaction:   CH2(COOH)2CH3C(O)OH + CO2
Reaction order:   1
Temperature:   200 - 700 K
Rate expression:   3.22x1012 [s-1]
Category:  Theory
Data type:   Transition state theory

View full bibliographic record.