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Title: The Thermal Decomposition of Alkyl Vinyl Ethers. Part III. Maximally Inhibited Decompositions of n-Propyl, Isobutyl, and 2-Methoxyethyl Vinyl Ethers
Journal: J. Chem. Soc. Perkin Trans. 2
Page(s):
Year: 1974
Reference type: Journal article
Squib: 1974BAM801
Reaction:
CH3OCH2CH2OCH=CH2 → CH3CHO + CH2=CHOCH3
Reaction order:
1
Temperature:
653 - 708
K
Pressure: 0.36 - 0.83 bar
Rate expression:
1.38x1011 [s-1] e-184581 [±1846 J/mole]/RT
Uncertainty:
1.23000002
Bath gas:
Cyclohexene
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 653 | 2.37E-4 |
| 675 | 7.18E-4 |
| 700 | 2.33E-3 |
| 708 | 3.33E-3 |