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Title: Reactions of oxygenated radicals in the gas phase. Part 12. The reactions of isopropylperoxy radical and alkenes
Journal: J. Chem. Soc. Perkin Trans. 2
Page(s):
Year: 1983
Reference type: Journal article
Squib: 1983SWA/WAD139
Reaction:
CH3CH=CH2 + (CH3)2CHO2 → Methyloxirane + (CH3)2CHO·
Reaction order:
2
Temperature:
303 - 408
K
Pressure: 1.00 bar
Rate expression:
1.38x10-12 [cm3/molecule s] e-67680 [±2711 J/mole]/RT
Uncertainty:
2.2899999618530273
Bath gas:
O2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Direct photolysis
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 303 | 2.97E-24 |
| 325 | 1.83E-23 |
| 350 | 1.10E-22 |
| 375 | 5.17E-22 |
| 400 | 2.01E-21 |
| 408 | 2.99E-21 |