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Chemical Sciences Division

Applied Chemicals and Materials Division

Author(s):   Tsuchiya, K.; Yamashita, K.; Miyoshi, A.; Matsui, H.
Title:   Studies on the reactions at atomic sulfur (3P) with H2, D2, CH4, C2H6, C3H8, n-C4H10, and i-C4H10
Journal:   J. Phys. Chem.
Volume:   100
Page(s):   17202 - 17206
Year:   1996
Reference type:   Journal article
Squib:   1996TSU/YAM17202-17206

Reaction:   iso-C4H10 + S → Other Products + SH
Reaction order:   2
Temperature:   830 - 1060 K
Pressure:  1.20E-2 bar
Rate expression:   3.39x10-11 [cm3/molecule s] e-33923 [±5421 J/mole]/RT
Uncertainty:   2.03999996
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Vis-UV absorption

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
830 2.48E-13
850 2.79E-13
875 3.20E-13
900 3.64E-13
925 4.11E-13
950 4.62E-13
975 5.16E-13
1000 5.73E-13
1025 6.33E-13
1050 6.96E-13
1060 7.22E-13