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Author(s):   Taniewski, M.
Title:   Kinetics and mechanism of the thermal decomposition of 4-methylpent-1-ene
Journal:   J. Chem. Soc.
Page(s):  
Year:   1965
Reference type:   Journal article
Squib:   1965TAN7436

Reaction:   (CH3)2CHCH2CH=CH2·CH2CH=CH2 + 2-C3H7
Reaction order:   1
Temperature:   743 - 803 K
Pressure:  3.33E-2 - 0.27 bar
Rate expression:   5.0x109 [s-1] e-184581 [J/mole]/RT
Bath gas:   (CH3)2CHCH2CH=CH2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Pressure measurement

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
743 5.28E-4
750 6.98E-4
775 1.81E-3
800 4.44E-3
803 4.92E-3