Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2020
Accessibility information
Author(s):   Kukui, A.; Roggenbuck, J.; Schindler, R.N.
Title:   Mechanism and rate constants for the reactions of Cl atoms with HOCl, CH3OCl and tert-C4H9OCl
Journal:   Ber. Bunsenges. Phys. Chem.
Volume:   101
Page(s):   281 - 286
Year:   1997
Reference type:   Journal article
Squib:   1997KUK/ROG281-286

Reaction:   CH3OCl + ·Cl → Products
Reaction order:   2
Temperature:   300 K
Pressure:  2.51E-3 - 3.51E-3 bar
Rate expression:   5.99x10-11 [±1.83x10-12 cm3/molecule s]
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Analytical technique:   Laser induced fluorescence

View full bibliographic record.