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 Author(s):   Wallington, T.J.; Dagaut, P.; Kurylo, M.J.
Title:   Ultraviolet absorption cross sections and reaction kinetics and mechanisms for peroxy radicals in the gas phase
Journal:   Chem. Rev.
Volume:   92
Page(s):   667 - 710
Year:   1992
Reference type:   Journal article
Squib:   1992WAL/DAG667-710

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1992WAL/DAG667-710   CH3O2· + CH3O2· → Products  250 - 600   9.22E-14       -3243   3.41E-13  2
  1992WAL/DAG667-710   CH3O2· + CH3O2· → CH3O· + CH3O· + O2  298   0.35           0.35  2
  Reference reaction:  CH3O2· + CH3O2· → Products 2
  1992WAL/DAG667-710   CH3O2· + HO2 → Products  228 - 573   5.65E-13       -5321   4.84E-12  2
  1992WAL/DAG667-710   CH3O2· + HO2 → CH3OOH + O2  295   0.92              2
  Reference reaction:  CH3O2· + HO2 → Products 2
  1992WAL/DAG667-710   CH3O2· + NO → CH3O· + NO2  240 - 370   3.90E-12       -1663   7.63E-12  2
  1992WAL/DAG667-710   CH3O2· + NO2 → CH3O2NO2  253 - 353   8.00E-12   -3.50       8.00E-12  2
  1992WAL/DAG667-710   CH3O2· + NO2 → CH3O2NO2  253 - 353   2.30E-30   -2.50       2.30E-30  3
  1992WAL/DAG667-710   CH3O2· + CH3C(O)OO(·) → CH2O + CH3C(O)OH + O2  298 - 368   4.10E-15       -1.75E04   4.71E-12  2
  1992WAL/DAG667-710   CH3O2· + CH3C(O)OO(·) → CH3O· + O2 + CH3C(O)O·  298 - 368   1.79E-09       1.50E04   4.27E-12  2
  1992WAL/DAG667-710   CH3O2· + CH3C(O)OO(·) → CH3O· + O2 + CH3C(O)O·  298   0.49           0.49  2
  Reference reaction:  CH3O2· + CH3C(O)OO(·) → Products 2
  1992WAL/DAG667-710   C2H5OO· + C2H5OO· → Products  260 - 380   8.50E-14       1039   5.59E-14  2
  1992WAL/DAG667-710   C2H5OO· + C2H5OO· → CH3CH2O· + CH3CH2O· + O2  298   0.63           0.63  2
  Reference reaction:  C2H5OO· + C2H5OO· → Products 2
  1992WAL/DAG667-710   C2H5OO· + HO2 → CH3CH2OOH + O2  250 - 380   5.60E-13       -5404   4.96E-12  2
  1992WAL/DAG667-710   C2H5OO· + NO → CH3CH2O· + NO2  298   9.00E-12           9.00E-12  2
  1992WAL/DAG667-710   C2H5OO· + NO2 → C2H5OONO2  298   1.00E-11           1.00E-11  2
  1992WAL/DAG667-710   C2H5OO· + NO2 → C2H5OONO2  298   4.80E-29           4.80E-29  3
  1992WAL/DAG667-710   HO2 + HOCH2OO → Products  275 - 333   5.60E-15       -1.91E04   1.26E-11  2
  1992WAL/DAG667-710   HO2 + CH3C(O)OO(·) → Products  253 - 368   4.30E-13       -8647   1.41E-11  2
  1992WAL/DAG667-710   HO2 + HOCH2CH2O2· → Products  298   4.80E-12           4.80E-12  2
  1992WAL/DAG667-710   (CH3)3CO2 + (CH3)3CO2 → Other Products + O2  290 - 420   9.51E-12       3.23E04   2.04E-17  2
  1992WAL/DAG667-710   (CH3)2CHO2 + (CH3)2CHO2 → iso-C3H7OH + Acetone + O2  300 - 473   4.10E-14       1.20E04      2
  1992WAL/DAG667-710   (CH3)2CHO2 + (CH3)2CHO2 → (CH3)2CHO· + (CH3)2CHO· + O2  300 - 373   2.31E-12       2.13E04      2
  1992WAL/DAG667-710   NO + CF3O2 → NO2 + CF3O  230 - 430   1.45E-11   -1.20       1.45E-11  2
  1992WAL/DAG667-710   NO + CCl3O2 → NO2 + CCl3O  230 - 430   1.69E-11   -1.00       1.69E-11  2
  1992WAL/DAG667-710   NO + CCl2FO2 → NO2 + CFCl2O  230 - 430   1.45E-11   -1.30       1.45E-11  2
  1992WAL/DAG667-710   NO + CClF2OO → NO2 + CF2ClO  230 - 430   1.60E-11   -1.50       1.60E-11  2
  1992WAL/DAG667-710   NO2 + CF3O2 → CF3OONO2  233 - 373   5.99E-12   -2.50       5.99E-12  2
  1992WAL/DAG667-710   NO2 + CF3O2 → CF3OONO2  233 - 373   2.20E-29   -5.00       2.20E-29  3
  1992WAL/DAG667-710   NO2 + CCl3O2 → CCl3OONO2  233 - 373   5.99E-12   -2.50       5.99E-12  2
  1992WAL/DAG667-710   NO2 + CCl3O2 → CCl3OONO2  233 - 373   5.02E-29   -5.00       5.02E-29  3
  1992WAL/DAG667-710   NO2 + CCl2FO2 → CFCl2OONO2  298 - 373   5.99E-12   -2.50       5.99E-12  2
  1992WAL/DAG667-710   NO2 + CCl2FO2 → CFCl2OONO2  298 - 373   3.50E-29   -5.00       3.50E-29  3
  1992WAL/DAG667-710   NO2 + CClF2OO → CClF2OONO2  298   5.20E-12           5.20E-12  2
  1992WAL/DAG667-710   NO2 + CClF2OO → CClF2OONO2  298   3.50E-29           3.50E-29  3
  1992WAL/DAG667-710   HOCH2OO + HOCH2OO → HCOOH + CH2(OH)2 + O2  270 - 320   5.65E-14       -6236   6.99E-13  2
  1992WAL/DAG667-710   HOCH2OO + HOCH2OO → O2 + HOCH2O + HOCH2O  300   0.90              2
  Reference reaction:  HOCH2OO + HOCH2OO → Products 2
  1992WAL/DAG667-710   CH3C(O)OO(·) + CH3C(O)OO(·) → Other Products + O2  250 - 370   2.81E-12       -4407   1.66E-11  2
  1992WAL/DAG667-710   HOCH2CH2O2· + HOCH2CH2O2· → Products  298   1.36E-12           1.36E-12  2
  1992WAL/DAG667-710   HOCH2CH2O2· + HOCH2CH2O2· → O2 + HOCH2CH2O· + HOCH2CH2O·  298   0.18           0.18  2
  Reference reaction:  HOCH2CH2O2· + HOCH2CH2O2· → Products 2
  1992WAL/DAG667-710   n-C3H7O2 + n-C3H7O2 → Other Products + O2  298   2.91E-13           2.91E-13  2
  1992WAL/DAG667-710   CH2ClO2 + CH2ClO2 → Products  250 - 500   3.11E-13       -6111   3.66E-12  2
  1992WAL/DAG667-710   CH2ClO2 + CH2ClO2 → O2 + CH2ClO + CH2ClO  300   >0.90              2
  Reference reaction:  CH2ClO2 + CH2ClO2 → Products 2
  1992WAL/DAG667-710   CH3C(O)CH2OO· + CH3C(O)CH2OO· → Products  298   8.30E-12           8.30E-12  2
  1992WAL/DAG667-710   CH2ClCH2O2 + CH2ClCH2O2 → Products  298   2.09E-12           2.09E-12  2
  1992WAL/DAG667-710   CH2ClCH2O2 + CH2ClCH2O2 → O2 + CH2ClCH2O + CH2ClCH2O  300   0.70              2
  Reference reaction:  CH2ClCH2O2 + CH2ClCH2O2 → Products 2
  1992WAL/DAG667-710   CH2FO2 + CH2FO2 → Products  250 - 500   3.30E-13       -5820   3.46E-12  2
Search returned 46 records.