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Author(s):   Andersen, M.PS.; Nielsen, O.J.; Hurley, M.D.; Wallington, T.J.
Title:   Atmospheric chemistry of t-CF3CH = CHCl: products and mechanisms of the gas-phase reactions with chlorine atoms and hydroxyl radicals
Journal:   Phys. Chem. Chem. Phys.
Volume:   14
Page(s):   1735 - 1748
Year:   2012
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2012AND/NIE1735-1748

Reaction:   CF3CHClCHO + ·Cl → Products
Reaction order:   2
Reference reaction:   ·Cl + (E)-CF3CH=CHCl → Products
Reference reaction order:   2
Temperature:   296 K
Pressure:  0.93 bar
Rate expression:   1.44x10-1±3.8x10-2
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   By end product analysis
Analytical technique:   Fourier transform (FTIR)
Comments:   The average of the nine determinations with error limits that encompass the extremes of the individual determinations.

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