Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2020
Accessibility information
Author(s):   Andersen, M.PS.; Nielsen, O.J.; Hurley, M.D.; Wallington, T.J.
Title:   Atmospheric chemistry of t-CF3CH = CHCl: products and mechanisms of the gas-phase reactions with chlorine atoms and hydroxyl radicals
Journal:   Phys. Chem. Chem. Phys.
Volume:   14
Page(s):   1735 - 1748
Year:   2012
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2012AND/NIE1735-1748

Reaction:   CF3CHClCHO + ·Cl → Products
Reaction order:   2
Reference reaction:   ·Cl + (E)-CF3CH=CHCl → Products
Temperature:   296 K
Pressure:  0.93 bar
Rate expression:   7.5x10-12 [±2.0x10-12 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   By end product analysis
Analytical technique:   Fourier transform (FTIR)
Comments:   The average of the nine determinations with error limits that encompass the extremes of the individual determinations.

View full bibliographic record.