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Author(s):   Dijkstra, A.J.; Kerr, J.A.; Trotman-Dickenson, A.F.
Title:   Reactions of difluoroamino-radicals. Part III. Addition to olefins
Journal:   J. Chem. Soc. A
Page(s):  
Year:   1967
Reference type:   Journal article
Squib:   1967DIJ/KER105

Reaction:   (CH3)2C=CHCH3 + NF2 → CH3CH(NF2)C(CH3)2
Reaction order:   2
Temperature:   314 - 428 K
Rate expression:   1.66x10-15 [cm3/molecule s] e-42238 [J/mole]/RT
Bath gas:   N2F4
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
314 1.56E-22
325 2.70E-22
350 8.26E-22
375 2.17E-21
400 5.07E-21
425 1.07E-20
428 1.16E-20