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Author(s):   Davidson, I.M.T.; Barton, T.J.; Hughes, K.J.; Ijadi-Maghsoodi, S.; Revis, A.; Paul, G.C.
Title:   Kinetics of radical-forming homolyses in alkenyl- and tert-butyisilanes. The stability of α- and β-silicon-substituted alkyl radicals
Journal:   Organometallics
Volume:   6
Page(s):  
Year:   1987
Reference type:   Journal article
Squib:   1987DAV/BAR644

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1987DAV/BAR644   (CH3)3CCH2CH3tert-C4H9 + ·C2H5  723 - 985   1.26E16       3.20E05      1
  1987DAV/BAR644   (CH3)3SiCH2CH2CH=CH2 → Products  840 - 903   1.26E12       2.29E05      1
  1987DAV/BAR644   (CH3)3SiCH2CH2CH=CH2CH2=CHCH2CH2· + (CH3)3Si·  840 - 903   3.98E14       2.87E05      1
  1987DAV/BAR644   (CH3)3Si(CH2)3CH=CH2 → Products  783 - 852   6.31E11       2.12E05      1
  1987DAV/BAR644   (CH3)3Si(CH2)3CH=CH2 → CH2=CHCH2CH2CH2· + (CH3)3Si·  783 - 852   2.00E15       2.82E05      1
  1987DAV/BAR644   tert-C4H9CH2CH2Si(CH3)3 → (CH3)3Si· + (CH3)3CCH2CH2·  879 - 941   1.26E16       3.09E05      1
  1987DAV/BAR644   (CH3)2SiHCH2CH2CH=CH2 → Products  805 - 866   6.31E12       2.50E05      1
  1987DAV/BAR644   (CH3)2SiHCH2CH2CH=CH2·CH2CH=CH2 + (CH3)3Si·  805 - 866   3.16E15       2.86E05      1
  1987DAV/BAR644   (CH3)2SiH(CH2)3CH=CH2 → Products  773 - 848   3.16E11       2.08E05      1
  1987DAV/BAR644   (CH3)2SiH(CH2)3CH=CH2 → CH2=CHCH2CH2CH2· + (CH3)2SiH  773 - 848   2.51E15       2.83E05      1
  1987DAV/BAR644   (CH3)3SiCH2C(CH3)3 → Neopentyl + (CH3)3Si·  873 - 926   1.58E16       3.09E05      1

Search returned 11 records.