Kinetics Database Logo     Home
©NIST, 2022
Accessibility information
Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Contact Us to Submit an Article

Citation

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

DOC home page

NIST home page

MML home page

Chemical Sciences Division

Applied Chemicals and Materials Division

Author(s):   Kaiser, R.I.; Asvany, O.; Lee, Y.T.
Title:   Crossed Beam Reaction of Phenyl Radicals with Unsaturated Hydrocarbon Molecules. I. Chemical Dynamics of Phenylmethylacetylene (C6H5CCCH3; X1A') Formation from Reaction of C6H5 (X2A1) with Methylacetylene CH3CCH (X1A1)
Journal:   J. Chem. Phys.
Volume:   112
Page(s):   4994 - 5001
Year:   2000
Reference type:   Journal article
Squib:   2000KAI/ASV4994-5001

Reaction:   CH3CCH + Phenyl → Products
Reaction order:   2
Rate expression:   no rate data available
Category:  Experiment
Data type:   Mechanistic information only
Experimental procedure:   Molecular beam
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry
Comments:   Authors report on a crossed molcular beam study of the reaction under single collision conditions and collision energy of 140 kJ/mol. Reaction dynamics data are reported and the PES is calculated. The reaction mechanism is discussed.

View full bibliographic record.