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Author(s):   Kaiser, R.I.; Asvany, O.; Lee, Y.T.
Title:   Crossed Beam Reaction of Phenyl Radicals with Unsaturated Hydrocarbon Molecules. I. Chemical Dynamics of Phenylmethylacetylene (C6H5CCCH3; X1A') Formation from Reaction of C6H5 (X2A1) with Methylacetylene CH3CCH (X1A1)
Journal:   J. Chem. Phys.
Volume:   112
Page(s):   4994 - 5001
Year:   2000
Reference type:   Journal article
Squib:   2000KAI/ASV4994-5001

Reaction:   CH3CCH + Phenyl → Products
Reaction order:   2
Rate expression:   no rate data available
Category:  Experiment
Data type:   Mechanistic information only
Experimental procedure:   Molecular beam
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry
Comments:   Authors report on a crossed molcular beam study of the reaction under single collision conditions and collision energy of 140 kJ/mol. Reaction dynamics data are reported and the PES is calculated. The reaction mechanism is discussed.

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