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Author(s):   Knox, J.H.; Nelson, R.L.
Title:   Competitive chlorination reactions in the gas phase: hydrogen and C1-C5 saturated hydrocarbons
Journal:   Trans. Faraday Soc.
Volume:   55
Year:   1959
Reference type:   Journal article
Squib:   1959KNO/NEL937

Reaction:   iso-C4H10 + ·Cliso-C4H9 + HCl
Reaction order:   2
Reference reaction:   C2H6 + ·Cl·C2H5 + HCl
Reference reaction order:   2
Temperature:   193 - 593 K
Pressure:  0.67 bar
Rate expression:   1.3 e923 [±101 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
193 2.31E0
200 2.26E0
225 2.13E0
250 2.03E0
275 1.95E0
300 1.88E0
325 1.83E0
350 1.79E0
375 1.75E0
400 1.72E0
425 1.69E0
450 1.66E0
475 1.64E0
500 1.62E0
525 1.61E0
550 1.59E0
575 1.58E0
593 1.57E0