Author(s):   Kern, R.D.; Singh, H.J.; Wu, C.H.
Title:   Thermal decomposition of 1,2 butadiene
Journal:   Int. J. Chem. Kinet.
Volume:   20
Page(s):
Year:   1988
Reference type:   Journal article
Squib:   1988KER/SIN731

Associated entries:

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Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Squib	Reaction	Temp [K]	A	Ea [J/mole]	Order
1988KER/SIN731	C₂H₂ + CH₂=CHCH=CH· → Benzene + H·	1300 - 2000	8.30E-13	1.55E04	2
1988KER/SIN731	1,3-Butadiene → C₂H₃ + C₂H₃	1300 - 2000	3.07E12	2.79E05	1
1988KER/SIN731	1,3-Butadiene + ·CH₃ → CH₄ + CH₂=CHCH=CH·	1300 - 2000	1.16E-10	7.74E04	2
1988KER/SIN731	1,3-Butadiene + CH₂=C=CH → CH₂=C=CH₂ + CH₂=CHCH=CH·	1300 - 2000	1.66E-11	9.40E04	2
1988KER/SIN731	CH₂=C=CH₂ + CH₂=CHCH=CH· → Toluene + H·	1300 - 2000	3.32E-13	1.55E04	2
1988KER/SIN731	1,2-butadiene → 1,3-Butadiene	1300 - 2000	1.50E13	2.84E05	1
1988KER/SIN731	1,2-butadiene → ·CH₃ + CH₂=C=CH	1300 - 2000	1.00E12	2.49E05	1
1988KER/SIN731	1,2-butadiene + ·CH₃ → Other Products + CH₄	1300 - 2000	1.16E-10	7.74E04	2
1988KER/SIN731	1,2-butadiene + H· → Other Products + H₂	1300 - 2000	1.66E-10	6.07E04	2
1988KER/SIN731	1,2-butadiene + H· → C₂H₄ + C₂H₃	1300 - 2000	6.64E-13		2
1988KER/SIN731	·CH₃ + ·CH₃ → C₂H₄ + H₂	1300 - 2000	1.66E-08	1.38E05	2
1988KER/SIN731	C₂H₃ → C₂H₂ + H·	1300 - 2000	5.81E-12	8.98E04	2

Search returned 12 records.