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Title: The reactions of alkyl radicals. Part VI. The reactions of methyl radicals with aliphatic aldehydes
Journal: J. Chem. Soc.
Page(s):
Year: 1960
Reference type: Journal article
Squib: 1960BIR/TRO2059
Reaction:
CH3CHO + ·CH3 → CH4 + CH3CO
Reaction order:
2
Reference reaction:
·CH3 + ·CH3 → C2H6
Temperature:
395 - 447
K
Pressure: 4.87E-2 - 5.96E-2 bar
Rate expression:
1.32x10-12 [cm3/molecule s] e-31761 [±956 J/mole]/RT
Uncertainty:
1.25999999
Bath gas:
(tert-C4H9O)2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 395 | 8.32E-17 |
| 400 | 9.39E-17 |
| 425 | 1.65E-16 |
| 447 | 2.56E-16 |