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Author(s):   Birrell, R.N.; Trotman-Dickenson, A.F.
Title:   The reactions of alkyl radicals. Part VI. The reactions of methyl radicals with aliphatic aldehydes
Journal:   J. Chem. Soc.
Page(s):  
Year:   1960
Reference type:   Journal article
Squib:   1960BIR/TRO2059

Reaction:   (CH3)2CHCHO + ·CH3CH4 + (CH3)2CHC=O
Reaction order:   2
Reference reaction:   ·CH3 + ·CH3C2H6
Temperature:   395 - 448 K
Pressure:  5.71E-2 - 6.87E-2 bar
Rate expression:   6.61x10-12 [cm3/molecule s] e-36417 [±1089 J/mole]/RT
Uncertainty:   1.58000004
Bath gas:   (tert-C4H9O)2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
395 1.01E-16
400 1.16E-16
425 2.21E-16
448 3.75E-16