Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Kubat, P.; Pola, J.
Title:   On the characterization of CO2 laser photosensitized reactions
Journal:   Collect. Czech. Chem. Commun.
Volume:   50
Page(s):   1537 - 1542
Year:   1985
Reference type:   Journal article
Squib:   1985KUB/POL1537-1542

Reaction:   CH3CCl3CH2=CCl2 + HCl
Reaction order:   1
Temperature:   1770 - 2900 K
Pressure:  0.36 bar
Rate expression:   2.0x1014 [s-1] e-230311 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Sensitized photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1770 3.19E7
1800 4.15E7
1900 9.32E7
2000 1.93E8
2100 3.74E8
2200 6.81E8
2300 1.18E9
2400 1.94E9
2500 3.08E9
2600 4.72E9
2700 7.01E9
2800 1.01E10
2900 1.42E10