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Accessibility information
Author(s):   Huybrechts, G.; Hubin, Y.; Van Mele, B.
Title:   Pyrolysis of 1,1,1-trichloroethane in the absence and the presence of added HCl and/or CCl4
Journal:   Int. J. Chem. Kinet.
Volume:   21
Page(s):   575 - 591
Year:   1989
Reference type:   Journal article
Squib:   1989HUY/HUB575-591

Reaction:   CH3CCl3CH2=CCl2 + HCl
Reaction order:   1
Temperature:   587 - 658 K
Pressure:  5.33E-2 - 0.20 bar
Rate expression:   7.08x1013 [s-1] e-226154 [J/mole]/RT
Uncertainty:   1.07000005
Bath gas:   CH3CCl3
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
587 5.32E-7
600 1.45E-6
625 8.90E-6
650 4.75E-5
658 7.90E-5