Author(s):   Smith, I.W.M.; Wrigley, D.J.
Title:   Time resolved vibrational chemiluminescence: Rate constants for the reactions F + HBr, HI → HF + Br, I and for the relaxation of HF(μ=6) by HBr, HI, CO₂, N₂O, CO, N₂ and O₂
Journal:   Chem. Phys.
Volume:   63
Page(s):
Year:   1981
Reference type:   Journal article
Squib:   1981SMI/WRI321

Associated entries:

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Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Plot		Squib		Reaction		Temp [K]		A		n		Ea [J/mole]		k(298.00 K)		Order
		1981SMI/WRI321		HI + ·F → HF + I		295		5.60E-11								2
		1981SMI/WRI321		HBr + ·F → HF + Br·		295		6.19E-11								2

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