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Author(s):   Han, L.; Siekmann, F.; Zetzsch, C.
Title:   Rate Constants for the Reaction of OH Radicals with Hydrocarbons in a Smog Chamber at Low Atmospheric Temperatures
Journal:   Atmosphere
Volume:   9
Page(s):  
Year:   2018
Reference type:   Journal article
Squib:   2018HAN/SIE320

Reaction:   (CH3)3CCH2CH3 + ·OH → Products
Reaction order:   2
Temperature:   288 K
Pressure:  1.01 bar
Rate expression:   2.07x10-12 [±3.0x10-14 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   Rate constant value was also obtained at 248 K. This value is presented in Table 2S of the Supporting Information for the article. Toluene and n-pentane were used as reference compounds. The error bars are 2σ.

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