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Title: FTIR product study of the Cl-initiated oxidation of CH3Cl: evidence for HCl elimination from the chloromethoxy radical
Journal: J. Phys. Chem.
Volume: 98
Page(s): 5679 - 5685
Year: 1994
Reference type: Journal article
Squib: 1994KAI/WAL5679-5685
Reaction:
HCO + Cl2 → HC(O)Cl + ·Cl
Reaction order:
2
Reference reaction:
HCO + O2 → CO + HO2
Reference reaction order:
2
Temperature:
296
K
Pressure: 1.60E-2 - 0.93 bar
Rate expression:
1.15±1.2x10-1
Bath gas:
N2
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Direct photolysis
Analytical technique:
Fourier transform (FTIR)
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