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Title: Catalysis by hydrogen halides in the gas phase. IX. Tertiary butyl ethyl ether and hydrogen bromide
Journal: Aust. J. Chem.
Volume: 19
Page(s): 75 - 84
Year: 1966
Reference type: Journal article
Squib: 1966STI/WAT75-84
Reaction:
tert-C4H9OC2H5 → C2H5OH + iso-C4H8
Reaction order:
2
Temperature:
536 - 610
K
Pressure: 5.33E-2 - 0.40 bar
Rate expression:
9.55x10-13 [cm3/molecule s] e-104762 [J/mole]/RT
Bath gas:
HBr
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Pressure measurement
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 536 | 5.90E-23 |
| 550 | 1.07E-22 |
| 575 | 2.91E-22 |
| 600 | 7.24E-22 |
| 610 | 1.02E-21 |