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Accessibility information
Author(s):   Serinyel, Z.; Black, G.; Curran, H.J.; Simmie, J.M.
Title:   A Shock Tube and Chemical Kinetic Modeling Study of Methy Ethyl Ketone Oxidation
Journal:   Combust. Sci. Technol.
Volume:   182
Page(s):   574 - 587
Year:   2010
Reference type:   Journal article
Squib:   2010SER/BLA574-587

Reaction:   ·CH3 + CH3C(O)CH2(·)C2H5COCH3
Reaction order:   2
Temperature:   1200 - 1800 K
Rate expression:   5.18x10-11 [cm3/molecule s] (T/298 K)-0.32
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other
Pressure dependence:   Rate constant is high pressure limit

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
1200 3.31E-11
1250 3.27E-11
1300 3.23E-11
1350 3.19E-11
1400 3.16E-11
1450 3.12E-11
1500 3.09E-11
1550 3.05E-11
1600 3.02E-11
1650 2.99E-11
1700 2.97E-11
1750 2.94E-11
1800 2.91E-11