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Author(s):   Forst, W.; Caralp, F.
Title:   Microcanonical variational theory of radical recombination by inversion of interpolated partition function. Part 2 - CX3 + O2 (X = H, F, Cl)
Journal:   J. Chem. Soc. Faraday Trans.
Volume:   87
Page(s):   2307 - 2315
Year:   1991
Reference type:   Journal article
Squib:   1991FOR/CAR2307-2315

Reaction:   ·CH3 + O2CH3O2·
Reaction order:   2
Temperature:   298 - 582 K
Rate expression:   1.23x10-12 [cm3/molecule s] (T/298 K)1.19
Bath gas:   Ar
Category:  Experiment
Data type:   RRK(M) extrapolation

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 1.23E-12
300 1.24E-12
325 1.36E-12
350 1.49E-12
375 1.62E-12
400 1.75E-12
425 1.88E-12
450 2.01E-12
475 2.14E-12
500 2.28E-12
525 2.41E-12
550 2.55E-12
575 2.69E-12
582 2.73E-12