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Accessibility information
Author(s):   Liu, D.; Khaled, F.; Giri, B.R.; Assaf, E.; Fittschen, C.; Farooq, A.
Title:   H-Abstraction by OH from Large Branched Alkanes: Overall Rate Measurements and Site-Specific Tertiary Rate Calculations
Journal:   J. Phys. Chem. A
Volume:   121
Page(s):   927 - 937
Year:   2017
Reference type:   Journal article
Squib:   2017LIU/KHA927-937

Reaction:   2,3-Dimethylpentane + ·OH → Other Products + H2O
Reaction order:   2
Temperature:   979 - 1294 K
Pressure:  1.52 bar
Rate expression:   3.04x10-10 [cm3/molecule s] e-19689 [J/mole]/RT
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Pressure dependence:   None reported
Experimental procedure:   Shock tube
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
979 2.71E-11
1000 2.85E-11
1025 3.02E-11
1050 3.19E-11
1075 3.36E-11
1100 3.53E-11
1125 3.70E-11
1150 3.88E-11
1175 4.05E-11
1200 4.23E-11
1225 4.40E-11
1250 4.57E-11
1275 4.75E-11
1294 4.88E-11