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Author(s):   Alecu, I.M.; Gao, Y.D.; Hsieh, P.C.; Sand, J.P.; Ors, A.; McLeod, A.; Marshall, P.
Title:   Studies of the kinetics and thermochemistry of the forward and reverse reaction Cl+C6H6=HCl+C6H5
Journal:   J. Phys. Chem. A
Volume:   111
Page(s):   3970 - 3976
Year:   2007
Reference type:   Journal article
Squib:   2007ALE/GAO3970-3976

Reaction:   Iodobenzene + ·Cl → Products
Reaction order:   2
Temperature:   300 - 750 K
Rate expression:   5.3x10-12 [cm3/molecule s] e2800 [J/mole]/RT
Rate constant is an upper limit.
Category:  Review
Data type:   Experimental value and limited review
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Resonance fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
300 1.63E-11
325 1.49E-11
350 1.39E-11
375 1.30E-11
400 1.23E-11
425 1.17E-11
450 1.12E-11
475 1.08E-11
500 1.04E-11
525 1.01E-11
550 9.78E-12
575 9.52E-12
600 9.29E-12
625 9.08E-12
650 8.90E-12
675 8.73E-12
700 8.57E-12
725 8.43E-12
750 8.30E-12