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Accessibility information
Author(s):   Westmoreland, P.R.; Dean, A.M.; Howard, J.B.; Longwell, J.P.
Title:   Forming benzene in flames by chemically activated isomerization
Journal:   J. Phys. Chem.
Volume:   93
Page(s):   8171 - 8180
Year:   1989
Reference type:   Journal article
Squib:   1989WES/DEA8171-8180

Reaction:   C2H2 + HCCCHCH· → Benzyne +
Reaction order:   2
Temperature:   400 - 1600 K
Pressure:  1.01 bar
Rate expression:   5.38x10-19 [cm3/molecule s] (T/298 K)6.48 e-27770 [J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   RRK(M) extrapolation

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
400 8.57E-22
500 1.93E-20
600 1.92E-19
700 1.15E-18
800 4.97E-18
900 1.70E-17
1000 4.87E-17
1100 1.22E-16
1200 2.77E-16
1300 5.76E-16
1400 1.12E-15
1500 2.05E-15
1600 3.58E-15