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Accessibility information
Author(s):   Falconer, W.E.; Knox, J.H.; Trotman-Dickenson, A.F.
Title:   Competitive oxidations. Part II. The lower alkanes and cyclopropane
Journal:   J. Chem. Soc.
Page(s):   782 - 791
Year:   1961
Reference type:   Journal article
Squib:   1961FAL/KNO782-791

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1961FAL/KNO782-791   CH4 + O2·CH3 + HO2  830   <0.36              2
  Reference reaction:  C2H6 + O2·C2H5 + HO2 2
  1961FAL/KNO782-791   C2H6 + O2·C2H5 + HO2  601 - 768   0.14       -6693      2
  Reference reaction:  neo-C5H12 + O2HO2 + Neopentyl 2
  1961FAL/KNO782-791   C3H8 + O2 → Other Products + HO2  583 - 693   <0.50              2
  Reference reaction:  iso-C4H10 + O2 → Other Products + HO2 2
  1961FAL/KNO782-791   C3H8 + O2 → Other Products + HO2  583 - 693   0.67              2
  Reference reaction:  iso-C4H10 + O2 → Other Products + HO2 2
  1961FAL/KNO782-791   Cyclopropane + O2Cyclopropyl + HO2  601 - 689   0.45              2
  Reference reaction:  C2H6 + O2·C2H5 + HO2 2
  1961FAL/KNO782-791   neo-C5H12 + O2HO2 + Neopentyl  599 - 765   0.26       -4182      2
  Reference reaction:  iso-C4H10 + O2 → Other Products + HO2 2

Search returned 6 records.