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Title: Temperature dependence of the rates of addition of oxygen atoms to olefins
Journal: J. Chem. Phys.
Volume: 33
Page(s): 1063 - 1067
Year: 1960
Reference type: Journal article
Squib: 1960CVE1063-1067
Reaction:
(CH3)2C=CHCH3 + O· → Products
Reaction order:
2
Reference reaction:
Cyclopentene + O· → Products
Reference reaction order:
2
Temperature:
299 - 392
K
Pressure: 1.47E-2 - 4.20E-2 bar
Rate expression:
1.18 e2029 [J/mole]/RT
Bath gas:
(CH3)2C=CHCH3
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Sensitized photolysis
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [] |
|---|---|
| 299 | 2.67E0 |
| 300 | 2.66E0 |
| 325 | 2.50E0 |
| 350 | 2.37E0 |
| 375 | 2.26E0 |
| 392 | 2.20E0 |