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Accessibility information
Author(s):   Cvetanovic, R.J.
Title:   Temperature dependence of the rates of addition of oxygen atoms to olefins
Journal:   J. Chem. Phys.
Volume:   33
Page(s):   1063 - 1067
Year:   1960
Reference type:   Journal article
Squib:   1960CVE1063-1067

Reaction:   (CH3)2C=CHCH3 + → Products
Reaction order:   2
Reference reaction:   Cyclopentene + → Products
Reference reaction order:   2
Temperature:   299 - 392 K
Pressure:  1.47E-2 - 4.20E-2 bar
Rate expression:   1.18 e2029 [J/mole]/RT
Bath gas:   (CH3)2C=CHCH3
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Sensitized photolysis
Analytical technique:   Mass spectrometry

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
299 2.67E0
300 2.66E0
325 2.50E0
350 2.37E0
375 2.26E0
392 2.20E0